Sparkplugs are supposed to last as long as 120K miles. Some tend to change them sooner as part of preventative maintenance. PCV valve needs replaced whenever it is clogged up - audible check or they are cheap enough to replace every year (~$5-$8).
Once you have the plasitic cover off - you need to remove the coil on plug modules. Might help to disconnect the wiring harness to each coil and remove the 10mm bolt holding the wire loom down (give you a bit more room to wiggle those coil packs out). After you remove them - might be a very good idea to blow out the sparkplug holes with compressed air to reduce the chance of debris falling into the sparkplug hole. Remove the plugs with the appropriate sparkplug wrench and a good sized extension (assume that the engine is cool enough to work on - removing plugs on a hot engine increases the chance to strip threads out). Pull each plug out, replace one at a time or all at once (whatever is easiest for you - probably safer one at a time to minimize debris falling into the hole). Coat the threads of the new plug with a little antiseize to help prevent them galling to the head - installation is reverse of removal.
PCV is on the valvecover closest to the brake booster on the driver's side of the car. Look for a rubber tube that routes from the throttlebody to the rear most corner of the valvecover - if you pull the hose off, the PCV barb will be sticking out. Need to put a large adjustable wrench or similar to remove it.