Sure, whatever is easiest for you. This system is completely different than previous designs, no firing order to mess up, unless you tried to take apart the wiring, etc. Dropping the #1 cylinder igniter into the #3 cylinder won't hurt you at all - all the igniters are identical. But, if you want to keep them with their respective cylinders - that works too. Some cases, might make more sense - like if you are diagnosing a misfire or ignition issue - want to keep them right where they are until you get around to check them out.
As for the TB cleaning - since yours is DBW, there are some things you want to make sure you keep an eye on. On the old cable throttlebodies - you just remove the tube running from the airbox to the throttlebody - exposing the TB. Then just gently force the blade up and clean around it. In your case - you CANNOT do that without possibly damaging the servo on the throttlebody.
Two options: First option, if you have a helper - you can have them put the ignition to RUN, but not start the car - throttlebody will be getting power to the servo and may make some noise (normal) - have them depress the accelerator to open the butterfly valve - then you can clean around it. Nice thing about this option - TB stays in the car and you still get a decent cleaning. Second option - might be the easiest for many, just remove the throttlebody. Be sure to disconnect the power correctly - note that some alarm systems / security systems might get upset if you do this - remove the throttlebody. If you are careful, you can minimize the amount of coolant lost (you have to remove two coolant lines from the TB), and may be able to reuse the gasket - most cases, better to replace it. This will make sure you clean both sides without even have to move the butterfly blade at all. Some cases where the car is heavily neglected, this may be the way to go.
Some may ask why go through all this trouble - benefit is the throttle plate will close correctly. Many cases, you can get enough soot and varnish build up to actually "prop" the butterfly blade up. This will cause the TB to meter in more air than is required, if outside of the specified range, you can get engine performance issues. Shaky, unstable, uneven idle - hesitation when leaving from a dead stop, etc. In advanced cases, the car can actually stall on you. For less than 5 minutes of work (two person method) - a no brainer to add to your DIY list of tasks to do.
Make sure you use a O2/AFR sensor safe solvent, one made specifically for this sort of cleaning. Fortunately, most of them out there will work just fine. Just pick up a can that says throttlebody cleaner - chances are, it will say O2/AFR safe, all throttlebodies, teflon coated, etc. Some even come with a fancy spray wand for hard to reach places, all depends on what looks good to you.
Some swear by Lucas products, some like Amsoil, other major brands. I generally just pickup whatever is on sale - Valvoline, CRC, 3M, BG, etc.